Can getting really turned on cause me to ovulate? I mean off schedule, or in addition to having?

You need to go to a library and ask a librarian to show you where to find information about that. For one thing, most librarians are female, so they can show some understanding while helping you to find an answer. For another, you can get a lot more information than any stranger on the internet can provide. And third, you now know a source of information about any other questions you may have about your body.